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French: front perdu

English translation: until the solvent front is no longer visible







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GLOSSARY ENTRY (DERIVED FROM QUESTION BELOW)
French term or phrase:à front perdu
English translation:until the solvent front is no longer visible
Entered by:Helen Genevier
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1:58pm May 5, 2008Login or register (free) for more options.
French to English translations [PRO]
Science - Chemistry; Chem Sci/Eng / TLC
French term or phrase: front perdu
"Placer la plaque dans une enceinte à chromatographie préalablement saturée par le solvant de migration. Faire migrer le solvant à front perdu."

Helen Genevier
France
Clarification request(s) and response
Dr Jones: 2:19pm May 5, 2008: Peer comments on this answer (and responses from the answerer)
agree Dr. Johanna Schmitt: that was my first thought, too...
How can you grant an agree when there's no answer given ??!!
Karen Tkaczyk: 2:53pm May 5, 2008: Hello Dr Jones. What do you mean by the 'front' is always 'perdu'? The answer to that may solve Helen's problem. I'm not familiar with a front being 'lost'.
Helen Genevier: 3:04pm May 5, 2008: This doc already uses the expression "front de solvent" as solvant front, and in most of the tests it says to develp until the solvent front has reached a distance of 15 cm, but in one case it is "à front perdu". I even have pictures of the chromatograms and on one the line "front de solvent" is drawn on and on the other it is labelled migration à front perdu at the top. It all points to Karen's answer, i.e. developed until the front has disappeared off the end of the plate.
Helen Genevier: 3:05pm May 5, 2008: ... it'd be good to know if there's a dedicated expression for this

see explanation
Explanation:
Hi Helen,
I've never seen this before. All I can think of is that it means that you leave the plate in until the front runs all the way to the top of the plate, but I don't have anything to back that up with. If no-one else finds a solid answer I'll try to research it later and add a note.

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Note added at 2 hrs (2008-05-05 15:59:45 GMT)
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I can't find a dedicated term Helen, neither in two textbooks I have on the subject nor online.
I've only come across this as being accidental - the point usually being to get the Rf as you know. I have let the solvent run off the top of the plate by accident many times though - we never had a specific came for that in the lab, that I recall (apart from 'idiot'!)
Selected response from:

Karen Tkaczyk
United States
Note from asker to answerer
Thanks Karen and to everyone else for your helpful comments - I used until the solvent front is no longer visible
4 KudoZ points were awarded for this answer



Summary of answers provided
3 +3see explanation
Karen Tkaczyk
5 +1solvent frontDr Jones


  


Answers

6 mins   confidence: Answerer confidence 5/5 peer agreement (net): +1
solvent front

Explanation:
[PDF] solvent front (in chromatography)Format de fichier: PDF/Adobe Acrobat - Version HTML
solvent front (in chromatography). The front line of the eluent. O.B. 99. IUPAC Compendium of Chemical Terminology. 2nd Edition (1997)
www.iupac.org/goldbook/S05753.pdf - Pages similaires - À noter

paper chromatography- [ Traduire cette page ]An introduction to paper chromatography (including two way ... The left-hand diagram shows the paper after the solvent front has almost reached the top. ...
www.chemguide.co.uk/analysis/chromatography/paper.html - 17k - En cache - Pages similaires - À noter

Chromatography of amino acids- [ Traduire cette page ]Remove the paper from the apparatus, and use a pencil to mark the position of the solvent front. Up to 5 pieces of chromatography paper can be placed across ...
www.biotopics.co.uk/as/amino%20acid%20chromatography.html - 9k - En cache - Pages similaires - À noter


Dr Jones
France
Specializes in field
Native speaker of: Native in EnglishEnglish
PRO pts in category: 28

Peer comments on this answer (and responses from the answerer)
neutral Karen Tkaczyk: I think the question is about 'perdu' not 'front'
1 min
  -> Obviously, but the the 'front' is always 'perdu'...

agree Trinh Do: I've come across this term before
39 mins
  -> Merci Trinh
Login to enter a peer comment (or grade)


7 mins   confidence: Answerer confidence 3/5Answerer confidence 3/5 peer agreement (net): +3
see explanation

Explanation:
Hi Helen,
I've never seen this before. All I can think of is that it means that you leave the plate in until the front runs all the way to the top of the plate, but I don't have anything to back that up with. If no-one else finds a solid answer I'll try to research it later and add a note.

--------------------------------------------------
Note added at 2 hrs (2008-05-05 15:59:45 GMT)
--------------------------------------------------

I can't find a dedicated term Helen, neither in two textbooks I have on the subject nor online.
I've only come across this as being accidental - the point usually being to get the Rf as you know. I have let the solvent run off the top of the plate by accident many times though - we never had a specific came for that in the lab, that I recall (apart from 'idiot'!)

Karen Tkaczyk
United States
Specializes in field
Native speaker of: Native in EnglishEnglish
PRO pts in category: 159
Note from asker to answerer
Thanks Karen and to everyone else for your helpful comments - I used until the solvent front is no longer visible
Notes to answerer
Asker: Hi Karen, thanks. That's how I interpreted it too, but can only find 1 relevant ref in French and it's not enlightening.


Peer comments on this answer (and responses from the answerer)
agree Dr. Johanna Schmitt: that was my first thought, too, but I can't back it up either, something like "until the front has run out of the plate and is not visible any more"
4 mins
  -> Thanks

agree Isabelle Berquin: I couldn't find a dedicated term either but I agree with this interpretation - perhaps running the TLC longer than usual to resolve closely-migrating species, when Rf determination is not essential? Solvent migration will stop when it reaches the top.
11 hrs
  -> Thanks

agree Drmanu49
2 days6 hrs
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