'Observe' is perfectly correct in this context. 'Observe' is more analytical than just 'watch'. A couple of reliable refs for you:
www.footballreferee.org/articles_detail.php?id=18Cached
Referees must adopt the best position to **observe the players** and ball; when ... Geoff Thompson and Lord Triesman, leading football commentator John Motson, ...
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England v Montenegro: Phil Jagielka's emergence puts Rio ...
www.telegraph.co.uk/.../football/.../England-v-Montenegro-
8 Oct 2010 – He will watch and **observe** the players in training, as always, but if ... at the self-appointed Leaders in Football conference in London this week. ...