Jan 10, 2020 02:01
4 yrs ago
English term
Retroaldol/aldol mechanism
English to Russian
Science
Medical: Pharmaceuticals
A “Retroaldol/aldol intramolecular mechanism” was proposed by McLaughlin et al. as the mechanism of epimerization for paclitaxel (Scheme 1).
In this proposed mechanism, the hydroxyl hydrogen is transferred from C7 to the C9 carbonyl with concomitant aldehyde formation at C7, ring cleavage between C7 and C8, doublebond formation between C8 and C9, and hence enol formation at C9 in a concerted mechanism.
In this proposed mechanism, the hydroxyl hydrogen is transferred from C7 to the C9 carbonyl with concomitant aldehyde formation at C7, ring cleavage between C7 and C8, doublebond formation between C8 and C9, and hence enol formation at C9 in a concerted mechanism.
Proposed translations
(Russian)
4 +1 | механизм [внутримолекулярной] ретроальдольной/альдольной реакции | Boris Kimel |
4 | ретроальдольно-альдольный механизм | Pavel Altukhov |
Proposed translations
+1
5 hrs
Selected
механизм [внутримолекулярной] ретроальдольной/альдольной реакции
"внутримолекулярный ретроальдольный/альдольный механизм"
4 KudoZ points awarded for this answer.
Comment: "Спасибо, Борис."
5 hrs
ретроальдольно-альдольный механизм
n/a
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